Acids, equilibrium & kinetics · HL

Rate Order from Two Experiments Calculator (HL)

HL tool. This two-trial relation assumes other reactant concentrations and conditions are unchanged.

Your values

Start with the example or enter your own values. Use a dot for decimals and e for scientific notation.

Rate Order from Two Experiments Calculator (HL) inputs

Calculated locally. No account or input upload.

Result & working

Example

The calculator is loading. The worked example is also shown below.

The formula

r₂/r₁ = (c₂/c₁)ⁿ

n = ln(r₂/r₁)/ln(c₂/c₁)

k = r/cⁿ (for this one-variable form)

What the variables mean
SymbolMeaning
nOrder with respect to the changing reactant.

When to use this calculator

The order obtained from experimental data need not equal a stoichiometric coefficient. For a multivariable rate law, isolate one reactant at a time with the others effectively constant.

Worked example

The page opens with these example values. The result below is pre-generated for reference.

  1. r₂/r₁ = 0.08/0.02 = 4
  2. c₂/c₁ = 0.2/0.1 = 2
  3. n = ln(r₂/r₁)/ln(c₂/c₁) = 2
  4. k = r₁/c₁ⁿ = 0.02 / (0.1)^(2) = 2

order n = 2

Common mistakes

  • If c₂/c₁ = 1, the two trials cannot determine this order.